artificial photosynthesis: 1
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Artificial Photosynthesis System Using Localized Plasmons
Ammonia photosynthesis system involving hydrogen produced from water by visible and near-infrared light using an optical nano-antenna
To realize highly efficient artificial photosynthesis, we have used an optical nano-antenna made of metal nanostructures to convert solar energy to a wide range of wavelengths from visible to near-infrared, succeeding in hydrogen generation based on the photolysis of water and the photosynthesis of ammonia, which has recently attracted attention as an energy carrier.
Research
To realize highly efficient artificial photosynthesis, it is essential to convert the energy into chemical substances by constructing a system that utilizes solar energy of visible and near-infrared wavelengths, which are not used in conventional artificial photosynthesis. We have succeeded in designing and fabricating an optical nano-antenna that can effectively collect light of various wavelengths by changing the shape and arrangement of the metal nanostructures. We have also successfully photodisintegrated water to produce hydrogen and oxygen stoichiometrically using sunlight in a wide range of wavelengths from visible to near-infrared. This system has also enabled us to photosynthesize ammonia through photoreduction of nitrogen in the air. Ammonia is attracting attention as a next-generation energy carrier, but its synthesis requires high-temperature and -pressure conditions, which may cause a huge environmental burden. This system is expected to be used as a method for ammonia synthesis at normal temperature and pressure using sunlight.
Hiroaki Misawa Emeritus Professor