Hokkaido University Research Profiles

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7. Affordable and Clean Energy: 37

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  • 1. No Poverty
  • 2. Zero Hunger
  • 3. Good Health and Well-being
  • 4. Quality Education
  • 5. Gender Equality
  • 6. Clean Water and Sanitation
  • 7. Affordable and Clean Energy
  • 8. Decent Work and Economic Growth
  • 9. Industry, Innovation and Infrastructure
  • 10. Reduced Inequality
  • 11. Sustainable Cities and Communities
  • 12. Responsible Consumption and Production
  • 13. Climate Action
  • 14. Life Below Water
  • 15. Life on Land
  • 16. Peace and Justice Strong Institutions
  • 17. Partnerships to achieve the Goal
  • Equipment for Simultaneous Optimization of Quality and Quantity of Liquid Ice for Freshness Preservation

    Liquid ice optimization system for long-term freshness preservation of food

    We have developed a device that calculates the minimum required amount of food-grade liquid ice (slurry ice (salt water ice) or salt-free water ice) using a simple heat capacity calculation, and that also calculates the salt concentration, water/ice mixing ratio, and shelf life to determine the slurry ice temperature based on the overall heat transfer coefficient (container heat radiation parameter) of the storage container.

    Research

    The amount of produced slurry ice, which is useful for maintaining the freshness of marine animals, often exceeded the amount actually used because there was not a calculation method that took storage time into account. At our laboratory, we have developed a device to optimize the quality (salt concentration and water/ice mixing ratio) and quantity (shelf life) of slurry ice simultaneously and quickly on the spot based on the overall heat transfer coefficient of the storage container, as described earlier. Since this method can be applied to the production of fresh water-derived salt-free liquid ice, it can also be used for other food than marine animals (vegetables, fruits, and livestock), and we are currently working to obtain the rights to this invention.

  • A method to evaluate radio wave propagation characteristics of in-vehicle wireless access services by large-scale electromagnetic field analysis

    Toward optimal design of wireless environments

    We have conducted research in various fields where radio waves are applied, including the evaluation of complex and special propagation environments in airplanes and passenger railroad cars, internal exposure of the human body to radio waves, electromagnetic interference evaluation and mechanism estimation regarding body medical devices implanted in the body, and evaluation of electromagnetic field leakage in wireless power supply devices for electric vehicles.

    Research

    The radio propagation environment inside a vehicle is a special environment that differs from the conventional propagation model due to multiple reflections caused by the surrounding metal and the presence of fixtures and passengers inside. It is therefore necessary to evaluate the characteristics of radio wave propagation, including the effects of absorption and scattering of radio waves by the bodies of passengers, to estimate the quality of the wireless connection under actual operational conditions. However, it is difficult to evaluate the propagation characteristics by actual measurement or simple numerical analysis (e.g., ray tracing). This study addresses modeling of the propagation environment in vehicles, which has been difficult in the past, and realizes a simulation method in a very large analysis space by using a supercomputer.

  • All-solid-state Lithium Secondary Battery with an Inorganic Solid Electrolyte

    Preparation of sulfide solid electrolyte from the liquid phase

    We have successfully deposited sulfide solid electrolyte through a simple process of dissolving sulfide glass, which exhibits high lithium ion conductivity in an organic solvent, and drying the glass. We have also found that this method is applicable to coating of electrode-active materials.

    Research

    In all-solid-state lithium secondary batteries that use a lithium-ion conductive solid electrolyte, the construction of a good electrode-electrolyte interface is very important to realize high energy-density batteries. We have conducted this research to construct a good electrode-electrolyte interface by preparing sulfide solid electrolytes from the liquid phase. We prepared a homogeneous solution of Li2S-P2S5-based solid electrolytes by dissolving them in N-methylformamide (NMF), and successfully redepositing Li2S-P2S5-based solid electrolytes by removing NMF from the solution. This solution was mixed with LiCoO2, a cathode material, and solid electrolyte was coated on LiCoO2 by removing NMF. Using this solution, we produced an electrode composite. Then, using the obtained electrode composite and sulfide inorganic solid electrolyte, we successfully produced all-solid-state lithium batteries and confirmed the stable operation of the batteries.

  • Analysis of Thermo-acoustic Vibration Generated by Combustion Equipment

    Thermo-acoustic vibrations often occur in combustion devices and combustion gas exhaust systems, causing noise and reducing the life of the combustion devices. This is caused by acoustic pressure fluctuations coupled with heat generation fluctuations in combustion and exhaust systems. With this study, we analyze this physical process and investigate the suppression technology.

    Research

    Thermo-acoustic vibrations are often generated in combustion equipment and combustion gas exhaust systems, leading to noise generation and reduction of the life of combustion equipment. This is caused by acoustic pressure fluctuations linked to heat generation fluctuations in the combustion and exhaust systems, and we are analyzing the physical processes that cause these fluctuations and investigating techniques to suppress them. With this study, a single circular tube is filled with a combustible premixed gas that is ignited at one end, and a thermo-acoustic vibration phenomenon that occurs during flame propagation in the tube is used. Various boundary conditions (open end condition, direction of propagation, composition of the gas mixture, diameter and length of the propagating tube, structure of the flame surface, etc.) are applied to this propagation phenomenon to induce the thermo-acoustic vibration phenomenon, and the factors behind it can then be understood using the combustion instability analysis method. The vibration phenomena reproduced here are observed in a simplified system, but they are general phenomena and lead directly to the understanding of thermo-acoustic vibration phenomena that occur in actual combustion equipment and exhaust systems.

  • Detoxification and Removal of Nitrogen from Carbon Resources Using Nanoparticles

    Use of nanoparticles for fuel nitrogen pre-removal and high-temperature gas purification

    To establish principles for advanced utilization of carbon resources in harmony with the global environment is one of the most important research themes for the next generation. With this study, we aim to develop a catalytic process that can efficiently convert carbon resources into clean energy using nanoscale metal and metal oxide particles.

    Research

    Nitrogen in carbon resources (Fuel-N) is emitted as NOx and N2O during combustion. During high-temperature gasification, it is mainly converted to NH3, which becomes a source of NOx in later-stage gas combustion. With this study, we have worked on the development of a method to convert Fuel-N into harmless N2 through a pyrolysis process prior to combustion or gasification, and found that Ca ions supported by the ion-exchange method change into CaO nanoparticles during pyrolysis and catalyze the formation of N2 formation.
    We have also found that Fe ions, which are originally contained in lignite coal, and FeOOH, which is abundantly found in brown iron ore, readily become metallic iron nanoparticles during the heating process, and that N2 is selectively produced during the decomposition reaction of NH3, pyridine and pyrrole by this catalyst. Since these N-containing species are contained in the crude gas produced during coal gasification, we are working to develop a new high-temperature gas purification method for the removal of these compounds.

  • Development of Gd?Si?O?-based High-performance Scintillators and Their Application

    Development of high luminescence scintillators for radiation detectors

    Scintillators are materials that emit light by radiation and are used in medical diagnostic equipment, and for oil exploration and other purposes. Gd2Si2O7 (GPS) scintillators have excellent features such as high luminescence, high energy resolution and non-tidal dissolution, and can be made into single crystals, ceramic plates and powders.

    Research

    The Gd2Si2O7: Ce (GPS) single crystal scintillator has excellent features such as high luminescence (1.4 times that of NaI:Tl), high energy resolution, non-tidal and no self-radioactivity, and can be used in high temperature environments of 250°C or higher. The technology has been transferred to Oxide Corporation, and is now ready for use in SPECT and other applications. We have also established a stable manufacturing technology for 5 cm square GPS sintered plates. By combining a position sensitive photomultiplier tube, it is now possible to detect nuclear fuel materials emitting alpha rays, which were released in the Fukushima Daiichi Nuclear Power Plant accident, with high sensitivity. The prototype device succeeded in detecting nuclear fuel-induced α-ray-emitting radionuclides in an environment with nuclear fuel-induced α-ray-emitting radionuclides: natural radioactivity (radon progeny) = 1:200, which had been inconceivable with conventional devices.

  • Development of Polymer Electrolyte Fuel Cells with Excellent Sub-zero Start-up Performance

    Elucidation of micro-nano freezing phenomena in fuel cells

    We are visualizing the freezing phenomenon near the reaction layer in fuel cells, which cannot normally be observed, using an ultracold electron microscope. By combining electrochemical measurements, we are also elucidating the freezing phenomenon of produced water, which becomes a problem in cold climate applications, and are developing fuel cells with excellent sub-zero activation performance.

    Research

    In the polymer electrolyte fuel cell (PEFC), which is a highly efficient and clean energy conversion device, the water produced by the reaction passes through a catalyst layer pores of several tens of nanometers in diameter and is discharged into the gas diffusion layer and gas supply channel through the microporous layer (MPL), which is a porous layer with pores of several micrometers in diameter, as shown in the left figure below. In the activation in a sub-zero environment in cold regions, the produced water freezes, causing the power generation to stop and degrade. However, the phenomenon is on a micro-nano scale and is thus difficult to measure, so the phenomenon is still insufficiently understood. This study is aimed to clarify where the water freezes and what mechanism leads to performance shutdown and aging degradation. We will conduct microscopic observation, electrochemical measurement and catalyst layer model analysis to contribute to the improvement of activation resistance and extension of the service life. The middle figure below shows the catalyst layer filled with ice, and the right figure is a structural schematic of the catalyst layer modeled in the analysis.

  • Development of Structural Materials for Fusion and High Energy Reactors

    Iron-based composites with high thermal conductivity

    By appropriately arranging high thermal conductive materials in iron-based structural materials, the thermal conductivity of the entire structural materials can be dramatically improved. This will lead to the improvement of the efficiency of energy production and the reduction of radioactive waste, as well as the development of iron-based structural materials for fusion reactors and high energy reactor divertors, for which there has been no solution so far.

    Research

    This paper focuses on the low thermal conductivity of iron-based materials, which are expected to be used in actual DEMO reactors, with a view to the development of heat exchange devices facing to the plasma in operation, and is aimed at a significant improvement of thermal conductivity, which is considered to be the key to success. The 500°C temperature gradient near the cooling tube of the DEMO reactor divertor imposes a huge heat load that has never been experienced in engineering equipment before. On various iron-based materials (pure iron, reduced activation ferritic martensitic steel and oxide dispersion strengthened ferritic steel), Cu and W wires of high thermal conductivity are appropriately arranged to ensure strength as a structural material while serving as a heat sink.

  • Electrochemically Responsive Organic Dyes

    From electrochromism to multiple responses (fluorescence, circularity)

    Based on cationic organic dyes, which allow easy control of color tone, we offer a group of materials that can respond in multiple ways, including fluorescence and optical rotation (circular dichroism). This technology is designed to suppress the decomposition process of reduced species, and the bi-stability of oxidized and reduced species is such that exchange does not occur, even when they are mixed.

    Research

    Electrochromism is a general term for compounds that change their color tone in response to changes in external electrical potential. As materials that can undergo reversible color changes, they are attracting attention as light control materials for smart windows and display functions for electronic paper. Materials of which not only the color tone, but also fluorescence, optical rotation (circular dichroism), etc. can be changed, enable tailor-made responses according to the application.
    With this technology, we provide a group of substances with multiple responses based on cationic organic dyes of which the color tone can easily be controlled. The reduced species of cationic dyes are generally reactive, and the repeatability of the response is low, but with this technology, the decomposition process of the reduced species is suppressed by incorporating two cationic moieties. The bi-stability of the oxidized and reduced species, in which no exchanges occur, even when they are mixed, makes it possible to apply this technology to high-density recording materials.

  • Elucidation of Combustion Phenomena Using Microgravity Fields

    Combustion phenomena are accompanied by a local temperature rise, which always results in natural convection in the surrounding air . This complicates the phenomenon and makes it difficult to fundamentally understand it. In this study, we will try to understand the combustion phenomena from a fundamental standpoint by utilizing the microgravity environment to remove the natural convection.

    Research

    Combustion phenomena are accompanied by a local temperature rise, which always results in natural convection in the surrounding air . This complicates the phenomena and makes it difficult to understand the fundamentals. In this study, we will utilize the microgravity environment to remove the natural convection and understand the fundamental processes (diffusion, heat conduction, soot formation, ignition, flame propagation, etc.) of combustion phenomena, which will be useful for numerical prediction and modeling of combustion devices. Hokkaido University has an approximately 40-meter drop tower that can be used at any time, making it easy to conduct microgravity experiments, and is also involved in international joint research to conduct microgravity experiments using aircraft and the International Space Station. Thus, we are in a favorable environment to conduct combustion research using the microgravity environment.

  • Fire-safety Improvement Technology for Lithium-ion Batteries

    The use of lithium-ion batteries has been expanding rapidly due to their high energy density. On the other hand, since organic solvents are used in lithium-ion batteries, it is important to ensure their fire safety. With this study, we focus on the combustion phenomenon of organic solvents and study combustion inhibition technology.

    Research

    The use of lithium-ion batteries has been expanding rapidly due to their high energy density. On the other hand, since organic solvents are used in the battery electrolyte, it is important to ensure their fire safety. With this study, we intend to develop a method to quantify the effect of adding a combustion inhibitor to suppress the combustion of organic solvents, search for additives that are effective in suppressing combustion, and study the effect of the lithium salt contained in the electrolyte itself on the flammability of organic solvents. We also conduct modeling and numerical analysis of fire phenomena taking the elementary reaction kinetics of combustion in an electrolyte into consideration.

  • Geothermal Resource Monitoring and Risk Assessment of Induced Earthquakes

    Monitoring and risk assessment of geothermal resources through geophysical observations

    Evaluation of the subsurface structure necessary for geothermal resource development by gravity survey and precise determination of the seismic source. Monitoring of geothermal reservoir resources by precise gravity measurements and crustal deformation observations. Risk assessment of induced earthquakes associated with geothermal well development and research on seismic activity prediction.

    Research

    ○ For geothermal resource development, which has been actively promoted in recent years, geothermal reservoirs are examined through base structure surveys. We have been investigating the basement structure through gravity surveys, precise seismic source distribution, and seismic velocity structure analysis.
    ○ For geothermal power generation, steam is produced and hot water is returned to the underground, but it is necessary to monitor the level of the geothermal reservoir to ensure the sustainable use of resources. We will examine the appropriate resource utilization volume through physical assessment of the subsurface fluid conditions using precise gravity measurements and crustal deformation observations.
    ○ The injection of high-pressure fluids into geothermal wells may induce noticeable tremors and cause problems. We will provide guidelines for appropriate and sustainable resource development by developing a method to evaluate the risk of induced earthquakes based on such parameters as the crustal stress state in the geothermal development area, surrounding faults, the characteristics of the seismic activity, and fluid injection volume.

  • High-efficiency Semiconductor Solar Cells

    New-type solar cell consisting of a multi-striped semiconductor with orthogonal photon-photocarriers that was coupled to a waveguide.

    Temperature rise and device degradation are suppressed by simultaneous optimization of light absorption and photocarrier collection, as well as photoelectric conversion over the entire solar spectrum by multiple semiconductor stripes. This leads to the realization of a highly efficient 2-dimensional PhotoReceptoConversion Scheme (2DPRCS).

    Research

    In conventional solar cells, there is a trade-off between carrier collection and the number of absorbed photons because the photo carrier migration direction and the light travel direction are parallel. Based on the orthogonality between the carrier migration direction and the light travel direction, it was possible to optimize both the light absorption and the carrier collection efficiency. Since the sunlight is sequentially photoelectrically converted from high- to low-energy components over the entire spectrum, thermal dissipation is minimized and high efficiency can be achieved. A waveguide type light collection system with a light wave direction conversion membrane can realize a photovoltaic system that is resistant to diffuse light. By preventing high-energy photons from entering the mid-gap and narrow-gap semiconductors, bond degeneration can be prevented and the life of the device can be extended. It is possible to realize the ultimate concentrator solar cell system, which is strong even in cloudy weather, has high conversion efficiency close to the thermodynamic limit, and is highly reliable.

  • High-temperature Latent Heat Storage Microcapsules

    Core (alloy latent heat storage material) ? shell (Al2O3) type latent heat storage microcapsules capable of high-density heat storage in the high temperature range of over 500?C

    The latent heat storage method, which utilizes latent heat generated during the solid-liquid phase change, is attractive for its high-density heat storage capacity. Microencapsulation of latent heat storage material enables not only heat storage but also heat transport and heat control applications, and we have developed latent heat storage microcapsules that can be used in the high temperature range of over 500°C.

    Research

    An Al-base alloy with a melting point above 500°C was newly discovered as a latent heat storage material. By skillfully applying chemical conversion/oxidation treatment to the micro-particles of this alloy (approx. 20 μm or larger), we have succeeded in developing core (Al-base alloy) and shell (Al2O3) type latent heat storage microcapsules (Fig. 1). These microcapsules have high heat storage capacity of approximately five times that of solid sensible heat storage materials, and have excellent mechanical properties. Since the shell is made of Al2O3, it can also be treated as a ceramic particle. In other words, it is an epoch-making heat storage material of which the performance can be upgraded while maintaining the current use of ceramic sensible heat storage technology.

  • Infrared Metamaterials Produced by Microfabrication of High Temperature Resistant Materials

    Development of materials and devices that manipulate mid- to far-infrared radiation

    It is expected that it will be possible to make devices to control corresponding electromagnetic waves by creating heaters and diffraction gratings with patterns smaller than the mid- to far-infrared wavelengths. We are developing methods to fabricate thin films, stacks, and microstructures of metal carbides and oxides, and are studying their elemental characteristics.

    Research

    Materials that are finely processed on a scale of less than the wavelength of electromagnetic waves can control the reflection and transmission of electromagnetic waves (such materials are known as metamaterials). Mid- to far-infrared radiation, with wavelengths ranging from 3 μm to 1000 μm, can be used for the detection of molecules as it is an electromagnetic wave that is related to heat radiation and can excite molecular vibrations. Since it is a heat-related material, being heat-resistant would render it usable for applications that cannot be realized elsewhere. We are studying process technology for heat-resistant materials with various properties such as metal carbides and oxides, and are measuring the fundamental properties of these materials in the infrared region for application to metamaterial design. By fabricating metamaterials for mid- to far-infrared radiation, we aim to create narrow linewidth mid-infrared light emitting devices for molecular detection and materials for controlling radiation heat.

  • Low-power A/D Converters for Sensing

    Use of time to digital converter for A/D converter and its low power consumption

    Single-Slope A/D converters, which involve the simplest configuration, are used in various forms (image sensors, etc.). However, one drawback is their slow conversion speed. With this technique high speed and low power consumption can be achieved simultaneously.

    Research

    Single-Slope A/D converters convert analog values to time and then digitize them. By using the Time to Digital Converter (TDC), the conversion time can be greatly reduced. However, power consumption increases significantly. Intermittent operation of the TDC is effective to reduce the power consumption of the TDC part by a factor of several times ten, enabling both high speed and low power consumption. The features of this method are as follows:
    Realization of low-power, high-speed, small-area A/D converters
    ・Synchronization and consistency of two measurements with high precision and coarse accuracy are guaranteed in principle
    ・The A/D conversion characteristics are continuous and easy to correct.

  • Low-temperature Nitridation Method Using Sodium Amide

    Nitride and oxynitride synthesis without using ammonia gas cylinder

    This is a method used to convert oxides and other materials into nitrides and oxynitrides at low temperatures (300°C or less) by using a sodium amide melt to trigger a reaction with a highly concentrated and active nitrogen source. Nitrides and oxynitrides can be synthesized without having to prepare toxic ammonia gas cylinders.

    Research

    This is a new method for nitridation of oxides at low temperatures (300℃ or less). Conventional nitridation methods require the installation of toxic ammonia gas cylinders and toxic ammonia gas recovery facilities, and also use a large amount of ammonia due to the low ammonia gas usage rate. With the present method, the use of sodium amide as a flux minimizes the use of toxic ammonia and makes it possible to obtain oxynitride and nitride nanocrystals at low temperatures. Since sodium amide is a solid nitrogen source, it eliminates the need to install ammonia liquid cylinders. We have also discovered a method to synthesize oxynitrides by mixing chloride and sodium amide through an instantaneous temperature-programmed reaction.

  • MALDI Matrix for Sensitive and High-Resolution Structural Analysis of Unmodified Sialylated Glycans and Glycoconjugates

    We have developed a matrix that can ionize sialylated glycans and glycoconjugates without modifying the carboxylic acid moiety of the sialic acids, and can analyze them with high sensitivity and resolution (reflector mode) without desorption of the sialic acid residue.

    Research

    Sialylation (addition of sialic acid) of glycans and glycoconjugates is an important biomarker involved in various biological phenomena such as development, differentiation, disease, infection, and immunity. MALDI (matrix-assisted laser desorption/ionization) is a simple and sensitive soft ionization method. However, the ionization efficiency of unmodified sialic acid-containing glycans is low, and there is a problem that the spectrum becomes complicated due to cleavage of sialic acids or other reasons. With this technique, we succeeded in measuring sialylated glycans and glycoconjugates with high sensitivity and high resolution without undergoing any modification process by improving the addition system to the conventional matrix while suppressing sialic acid desorption. With the change in the cleavage pattern and the increased sensitivity, TOF/TOF analysis and pseudo-MS3 analysis can now be performed using ultra-trace samples. This method does not require chemical modification and separation steps, and enables reaction tracking and rapid sample analysis.

  • Monitoring the Output of Renewable Energy Generation and Measures Against Output Fluctuations

    Real-time monitoring of fluctuations in solar and wind power output and control of such fluctuations

    We have developed a method for extracting load power (A) and renewable energy output (B) from power flow information in which (A) and (B) coexist. Although (B) fluctuates greatly depending on the weather conditions, we have developed a control method to suppress fluctuations using storage batteries and a method to evaluate storage battery capacity.

    Research

    In this laboratory, we have developed a method to extract the output of renewable energy (RE) power generation hidden in the information of power flowing through distribution lines in real time by applying a signal analysis technique called independent component analysis (ICA). This method enables highly accurate output estimation without having to use preliminary information such as the installed PV capacity in the grid (Fig. 1).
    We have also developed a control method to compensate for RE power output fluctuations using storage batteries (Fig. 2) and simulation technology to estimate the storage battery capacity required to suppress output fluctuations for individual wind farms and mega solar power plants.

  • Multi -beam Ultra-high Voltage Electron Microscope and Materials Research

    Multi-beam science and engineering applications

    At the High-Voltage Electron Microscope (HVEM) Laboratory of Hokkaido University, the world’s first multi -quantum beam HVEM has been developed. It enables in-situ observation of microstructural changes on an atomic scale using multi-quantum beam irradiation.

    Research

    The world’s first multi-quantum beam HVEM (left)
    In 2014, we added an optical system that allows the use of multiple lasers, and developed a multi-quantum beam HVEM that allows in-situ observation at the atomic level under irradiation by multi-quantum beams, including ion, laser and electron beams. We are currently developing an in-situ spectroscopy system.

    Nanocrystal growth by UV irradiation (right)
    We have succeeded in growing ZnO nanocrystals by irradiating submerged plasma-treated Zn with UV light. We are now promoting research on the growth mechanism and its application.
    Scientific Report, 5, 11429(2015), AIP Advances, 7(2017) pp. 035220, Other reference: Nano Letters, 17(2017) pp. 2088-2093